Are you talking about sanding the edge down, or the face?
For the edge, I'd say no problem but you might be better off with something linear so that you can sand along the edge instead of back and forth across it.
If you mean sanding the face down, that's also structurally fine but it might be pretty challenging to get a good clear polish back on it at the end.
No big caveats for acrylic like there would be for, say, tempered glass. It's just a plain hunk of plastic. Maybe keep the speed down since you don't want heat buildup.
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